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105 Oxidation by hydrogen peroxide comprises two spin-allowed steps: Sulfenic acid formation (equation 5) involves nucleophilic attack by the thiolate and is slow for simple low molecular weight thiols (with second order rate constants of about 25 M −1 s −1 ) 106,107 but can be greatly accelerated enzymatically

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CYP1B1: a novel molecular biomarker predicts molecular subtype, tumor microenvironment, and immune response in 33 cancers