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Solution spectroscopy published in Biochemistry in 1982 indicated copper(II) equatorially coordinated by two or three nitrogen atoms at neutral pH, with three optical transitions at apparent pK values of 3.6, 9.2 and 11.4

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[DOI] [PubMed] [Google Scholar] 335.Eefting F, Rensing B, Wigman J, Pannekoek WJ, Liu WM, Cramer MJ, et al